Holders Spain was knocked out of the World Cup as Chile consigned them to a second straight defeat in Group B.
Eduardo Vargas finished off a well-worked Chile move by poking in a shot to give his side an early lead.
A mistake from Spain keeper Iker Casillas allowed Charles Aranguiz to smartly finish for add Chile’s second.
Diego Costa had a shot blocked when played through on goal and Sergio Busquets side-footed wide from five yards as Spain failed to recover, reports the BBC.
Australia 2-3 Holland
Chile 2-0 Spain